
Physical Chemistry
Surface chemistry Solutions
N
N
H
N
N
H
H
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
Ru
The diagram above illustrates how the reaction N (9) + 3 H2(9) + 2 NH3 (9) occurs on the surface of Ru (s). The rate of this reaction is determined by the amount of energy required to break the bond in N,. This bond is weakened when N,
is adsorbed on Ru (8). Based on this information, which of the following provides the best reason for the use of Ru (8) for the synthesis of NH, ?
It promotes the proper orientation of N and H atoms to form new N-H bonds.
B
It provides a reaction path with a lower activation energy.
C
It forms a bond between Ru and N that is stronger than the bond in N2.
D
It decreases the frequency of collisions between N2(9) and H2(9).