Question:

3. (25 points) Square planar Ir complexes have been widely studied in organometallic catalysis. Provided the following isomers a

3. (25 points) Square planar Ir complexes have been widely studied in organometallic catalysis. Provided
the following isomers answer the following questions:
CI
CN
CN
Cl
ir
Ir
CI
CN
NC
Cl
Isomer A
Isomer B
a.
What is the point group of each isomer?
Isomer A:
Isomer B:
b. Determine the reducible and irreducible representations corresponding to the CN stretching
of Isomer A.
c.
Determine the reducible and irreducible representations corresponding to the CN stretching
of Isomer B.

3. (25 points) Square planar Ir complexes have been widely studied in organometallic catalysis. Provided the following isomers answer the following questions: CI CN CN Cl ir Ir CI CN NC Cl Isomer A Isomer B a. What is the point group of each isomer? Isomer A: Isomer B: b. Determine the reducible and irreducible representations corresponding to the CN stretching of Isomer A. c. Determine the reducible and irreducible representations corresponding to the CN stretching of Isomer B.

Answer

-
OV
Anne
Part -10 the isomers of B
i
reduccible in nature on removal
ca
CN- will he stable
he cause
present at far poschon
to that of other Ce on CN-
(
chain
like
the
cuswer
of either
t
the charge
au parent

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