![TE 8C3 3C2 684 604
linear functions,
rotations
quadratic
functions
cubic
functions
A+1+1
+1
+1
+1
x² + y² +2²
xyz
+1
- 1
- 1
-
-1
+1
-1
- 1
- 1
+1
.
N
E +2 -1 +2 0 0
(272-x2-y? x²-y2)
T +3 0
(Ry, Ry, R)
[x(z”-y2), y(z?-x²), z(x²-y?)]
T +3 0
(x, y, z) (xy,](https://media.kunduz.com/media/question/seo/raw/20211119054927516916-3522013_NvwwfYbQ5.jpeg?w=256)
Inorganic Chemistry
D Block elements Solutions
TE 8C3 3C2 684 604
linear functions,
rotations
quadratic
functions
cubic
functions
A+1+1
+1
+1
+1
x² + y² +2²
xyz
+1
- 1
- 1
-
-1
+1
-1
- 1
- 1
+1
.
N
E +2 -1 +2 0 0
(272-x2-y? x²-y2)
T +3 0
(Ry, Ry, R)
[x(z”-y2), y(z?-x²), z(x²-y?)]
T +3 0
(x, y, z) (xy, xz, yz) (x”.y°, 2°) [x(z++y?), y(z²+x?), z(x²+y?)]
linear functions, quadratic cubic
C2 E C2 (2) (xz) (y)
rotations functions functions
A +1+1 +1 +1
x?, y?, 22 z’, x?z, y z
A2 +1+1 -1 - 1 Rz
xy xyz
B +1 -1 +1 -1 |x, Ry
XZ
|xz², x³, xy²
B2 +1 -1 - 1 +1 ly, R,
yz?, y’, x?y
cubic
C4 E 204 (2) C2 20 200
linear functions, quadratic
rotations functions
functions
A +1+1 +1+1 +1 z
x+y2, 22 z?, z(x2+y2)
A2 +1+1 +1 -1 - 1 R2
yz
BI
+1 -1
+1+1
-1
B
+1 -1
+1 -1
+1
x²-y² z(x2-y)
xyz
(xz, yz) (x2², yz?) (xy”, x²y) (x?,y)
xy
E
+20
-20
0
(x, y) (Ry, Ry)
2. (14 points) A student synthesized a new molecule of MX4 with either point group Td, Cav, or Cav each of
the following point group's character tables are reflected above.
A. None of these point groups result in the rule of mutual exclusion
(T/F)
B. List the possible Raman active modes for each point group
Td
C2v
Cav_
C. List the possible IR active modes for each point group
To
C2v
Cav_
